中国中药杂志

2018, v.43(05) 959-963

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黑果菝葜中2个新化学成分(英文)
Two new compounds from Smilax glaucochina

舒积成;刘敏;朱根华;刘荣华;邵峰;黄慧莲;
SHU Ji-cheng;LIU Min;ZHU Gen-hua;LIU Rong-hua;SHAO Feng;HUANG Hui-lian;Jiangxi University of Traditional Chinese Medicine;

摘要(Abstract):

从黑果菝葜中分离得到1个新的倍半萜(黑果菝葜萜醇A,1)和1个新的苯丙素苷化合物(黑果菝葜苷A,2),以及6个已知化合物,trichothecolone(3),β-D-(6-O-trans-feruloyl)fructofuranosyl-α-D-O-glucopyranoisde(4),3,4,5-三甲氧基-苯酚葡萄糖苷(5),(4R)-p-薄荷-1-烯-7,8-二醇-7-O-β-D-吡喃葡萄糖苷(6),柚皮素(7),大黄素-8-O-β-葡萄糖苷(8),根据NMR,MS等波谱方法和理化性质,并结合文献,鉴定了其化学结构。化合物3~8均为首次从此植物中分离得到。
A new sesquiterpenes named glaucochinarol A(1) and a new phenylpropane glycoside named glcacochinaside A(2),together with six known ones,including trichothecolone(3),β-D-(6-O-trans-feruloyl) fructofuranosyl-α-D-O-glucopyranoisde(4),3,4,5-trimethoxyphenyl-β-D-glucopyranoside(5),(4 R)-p-menth-1-ene-7,8-diol-7-O-β-D-glucopyranoside(6),naringenin(7),and emodin-8-O-β-glucoside(8) were isolated from smilax glaucochina warb. Their structures were elucidated on the basis of NMR,MS and published data. Compounds 3-8 were isolated from the species for this first time.

关键词(KeyWords): 黑果菝葜;倍半萜;苯丙素苷;黑果菝葜萜醇A;黑果菝葜苷A
Smilax glaucochina;sesquiterpene;phenylpropane glycoside;glaucochinarol A;glcacochinaside A

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金项目(31370376,81360628);; 江西省自然科学基金项目(20142BCB23023,2016BAB25119)

作者(Author): 舒积成;刘敏;朱根华;刘荣华;邵峰;黄慧莲;
SHU Ji-cheng;LIU Min;ZHU Gen-hua;LIU Rong-hua;SHAO Feng;HUANG Hui-lian;Jiangxi University of Traditional Chinese Medicine;

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