柳继锋;张雪梅;施瑶;江志勇;马云保;陈纪军;
LIU Jifeng1,ZHANG Xuemei1,SHI Yao2,JIANG Zhiyong1,MA Yunbao1,CHEN Jijun1 (1.State Key Laboratory of Phytochemistry and Plant Resources in West China,Kunming Institute of Botany,Chinese Academy of Sciences,Kunming 650204,China;2.Hawley & Hazel Chemical(ZS) Co.,Ltd,Zhongshan 528411,China)

• 1:中国科学院昆明植物研究所植物化学与西部植物资源国家重点实验室
• 2:好来化工(中山)有限公司

摘要(Abstract)：

目的:研究八角科Illiciaceae植物红茴香Illicium henryi根茎的化学成分。方法:应用硅胶,Sephadex LH-20,Rp-8,Rp-18等各种色谱技术进行分离纯化,根据化合物的理化常数和波谱数据鉴定其结构。结果:从红茴香根茎中分离得到12个化合物,分别鉴定为蛇菰脂醛素(1),aviculin(2),rubriflosides A(3),1,2-bis(4-hydroxy-3-methoxyphenyl)-1,3-propanediol(4),jasopyran(5),山柰酚(6),槲皮素(7),(2R,3R)-3,5,7,3′,5′-五羟基黄烷(8),3,4,5-trimethoxyphenyl-1-O-β-D-gluco-pyranoside(9),3,4-dimethoxyphenyl-1-O-β-D-glucopyranoside(10),松柏醛(11),芥子醛(12)。结论:化合物1~12均为首次从该植物中分离得到。
Objective: To study the chemical constituents of Illicium henryi.Method:Column chromatographic techniques using silica gel,Sephadex LH-20,Rp-8 and Rp-18 as packing materials were applied to isolate constituents.The structures of isolates were determined on the basis of spectroscopic data analyses.Result: Twelve compounds were isolated from the rhizomes of I.henryi,which were characterized as balanophonin(1),aviculin(2),rubriflosides A(3),1,2-bis(4-hydroxy-3-methoxyphenyl)-1,3-propanediol(4),jasopyran(5),kaempferol(6),quercetin(7),(2R,3R)-3,5,7,3′,5′-pentahydroxyflavan(8),3,4,5-trimethoxyphenyl-1-O-β-D-glucopyranoside(9),3,4-dimethoxyphenyl-1-O-β-D-glucopyranoside(10),coniferyl aldehyde(11),sinapaldehyde(12),respectively.Conclusion: All the isolates were obtained for the first time from this plant.

关键词(KeyWords)： 八角属;红茴香;木脂素;黄酮;化学成分
Illicium;Illicium henryi;lignans;flavonoids;chemical constituents

Abstract:

Keywords:

基金项目(Foundation):

作者(Author): 柳继锋;张雪梅;施瑶;江志勇;马云保;陈纪军;
LIU Jifeng1,ZHANG Xuemei1,SHI Yao2,JIANG Zhiyong1,MA Yunbao1,CHEN Jijun1 (1.State Key Laboratory of Phytochemistry and Plant Resources in West China,Kunming Institute of Botany,Chinese Academy of Sciences,Kunming 650204,China;2.Hawley & Hazel Chemical(ZS) Co.,Ltd,Zhongshan 528411,China)

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DOI:

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